Beilstein J. Org. Chem.2016,12, 245–252, doi:10.3762/bjoc.12.26
polymerization; (meth)acrylpolymers; neighboring group effects; solvent polarity; Introduction
Amino groups are important functionalities in polymer chemistry, e.g., for hardening various epoxy resins [1]. However, they easily react in an undesired side reaction with electron-poor double bonds of (meth
(Scheme 4).
Conclusion
It can be concluded from the above described results that the bromo-tert-butyloxycarbonyl group has a certain potential for the preparation of amino group containing functional (meth)acrylpolymers. Since the deprotection takes place under mild conditions in polar solvents, some
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Graphical Abstract
Figure 1:
Schematic representation of a deprotection taking the relatively high polarity of the transition st...